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Greenlist(tm) Bulletin 08/12/2005


This is the weekly bulletin of the TURI Library, reporting a selection of recently published titles we have acquired. Our pledge is to keep the bulletin relevant to your work and brief -- no more than 10 titles. You are welcome to send a message to jan@turi.org if you would like more information on any of the articles listed here.


Titles here, abstracts below them:
  1. Acute Illnesses Associated with Pesticide Exposure at Schools. July 2005
  2. Non-lead PVC Stabilizers for U.S. Wire and Cable Applications. August 2005
  3. Impact of technological development, market and environmental regulations on the past and future performance of chemical processes. July 2005
  4. New trends in pest control: the search for greener insecticides. June 2005
  5. Impact of Occupational Exposure on Lead Levels in Women. April 2005

 


1. Acute Illnesses Associated with Pesticide Exposure at Schools

AUTHOR Alarcon, William A.; Calver, Geoffrey M.; Blondell, Jerome M.; et al.

DATE 2005

SOURCE Journal of the American Medical Association (JAMA), v294 n4, July 27, 2005, pp455-465

ABSTRACT Pesticides continue to be used on school property, and some schools are at risk of pesticide drift exposure from neighboring farms, which leads to pesticide exposure among students and school employees. However, information on the magnitude of illnesses and risk factors associated with these pesticide exposures is not available. The goal of this study was to estimate the magnitude of and associated risk factors for pesticide-related illnesses at schools. It involved analysis of surveillance data from 1998 to 2002 of 2593 persons with acute pesticide-related illnesses associated with exposure at schools. Nationwide information on pesticide-related illnesses is routinely collected by 3 national pesticide surveillance systems: the National Institute for Occupational Safety and Health’s Sentinel Event Notification System for Occupational Risks pesticides program, the California Department of Pesticide Regulation, and the Toxic Exposure Surveillance System.

Incidence rates for 1998-2002 were 7.4 cases per million children and 27.3 cases per million school employee full-time equivalents. The incidence rates among children increased significantly from 1998 to 2002. Illness of high severity was found in 3 cases (0.1%), moderate severity in 275 cases (11%), and low severity in 2315 cases (89%). Most illnesses were associated with insecticides (n = 895, 35%), disinfectants (n = 830, 32%), repellents (n = 335, 13%), or herbicides (n = 279, 11%). Among 406 cases with detailed information on the source of pesticide exposure, 281 (69%) were associated with pesticides used at schools and 125 (31%) were associated with pesticide drift exposure from farmland. The investigators concluded that pesticide exposure at schools produces acute illnesses among school employees and students. To prevent pesticide-related illnesses at schools, implementation of integrated pest management programs in schools, practices to reduce pesticide drift, and adoption of pesticide spray buffer zones around schools are recommended.


2. Non-lead PVC Stabilizers for U.S. Wire and Cable Applications

AUTHOR Kroushl, Paul

DATE 2005

SOURCE Wire Journal International, v36 n8, August 2005, pp77-80

ABSTRACT :Lead stabilizers based on tribasic lead sulfate (TBLS) and dibasic lead phthalate are used in the majority of wire and cable applications in the U.S. These stabilizers have historically offered advantages over other stabilizer systems in terms of long term heat stability, electrical performance, and cost. Over the past 10 years, however, advances in calcium zinc stabilizer technology have dramatically closed the price and performance gap versus lead in wire and cable applications. Regulatory issues such as California Proposition 65 have also served to increase the interest in non-toxic stabilizer alternatives. Although none of the replacement stabilizer systems match the performance of lead in every criteria (heat stability, color hold, electrical performance, etc.), end users in some wire and cable applications have been able to cost-efficiently replace lead stabilizers with non-toxic calcium zinc stabilizer systems.


3. Impact of technological development, market and environmental regulations on the past and future performance of chemical processes

AUTHOR Mendivil, Ramon; Fischer, Ulrich; Hungerbuhler, Konrad

DATE 2005

SOURCE Journal of Cleaner Production, v13 n9, July 2005, pp869-880

ABSTRACT This work presents a systematic approach to introduce the evolution of technology, market and environmental regulations into process design, more specifically into the generation of retrofit alternatives. For this purpose the information on development of technology, economic and environmental performances is obtained. Firstly, the evolution of the technology for the production of a chemical and its precursors is analyzed. Afterwards, the development of the market situation regarding prices and demand together with the progress of the environmental regulations is studied. This allows for the assessment of the economic and environmental performance of the process over time. Finally, the economic and environmental assessment is used for the identification of process alternatives that can further improve the process performance in the future. This methodology is demonstrated using the production of hydrogen cyanide as a case study.


4. New trends in pest control: the search for greener insecticides

AUTHOR Lopez, Oscar; Fernandez-Bolanos, Jose G.; Gil, Maria Victoria

DATE 2005

SOURCE Green Chemistry, v7 n6, June 2005, pp431-442

ABSTRACT Insecticides have a pivotal role in our lives, not only for crop protection in agriculture, but also to avoid the spreading of harmful pests causing human diseases such as malaria. Due to economic and medical reasons, the design of effective agents that control these pests is quite an important task in agrochemical science and in the industrial sector. Nevertheless, the non-restricted use of highly toxic insecticides for several decades has provoked negative effects in the environment and the poisoning of non-targeted species. For these reasons, the development of selective and harmless insecticides is needed. A short overview of some of the recent advances in the chemistry of insecticides is presented, with a highlight of their greenness compared with classical insecticides. Synthesis, mode of action and environmental profile of pyrethroids, neonicotinoids, and insect growth regulators will be described. Furthermore, the use of biological insecticides such as spinosyns, azadirachtin, and Bacillus thuringiensis as green alternatives for synthetic insecticides will also be reviewed.


5. Impact of Occupational Exposure on Lead Levels in Women

AUTHOR Popovic, Marija; McNeill, Fiona E.; Chettle, David R.; et al.

DATE 2005

SOURCE Environmental Health Perspectives, v113 n4, April 2005, pp478-484

ABSTRACT In 1994, 207 women participated in a study designed to examine the effects of occupational exposure and various lifestyle factors on bone and blood lead levels. In vivo measurements of Pb concentrations in tibia were performed by X-ray fluorescence. All 108 former smelter employees and 99 referents provided blood samples and answered a questionnaire on lifestyle characteristics and the relevant medical history. Lead concentrations in tibia and blood were significantly higher in the exposed group. The difference in mean bone Pb concentrations of the two groups is markedly greater than the difference in the mean blood Pb concentrations, supporting the view that bone Pb measurements are a more reliable determinant of Pb body burden. Chronic exposure did not result in any statistically significant differences in adverse pregnancy outcomes. A significantly lower age at the onset of menopause in occupationally exposed women may suggest that Pb causes adverse changes in the pattern of estrus and menses. The exposed women had lower bone Pb concentrations than those found in most studies on predominantly male workers. Blood Pb concentrations remain increased in women long after the cessation of occupational exposure, reflecting the importance of the endogenous exposure. The endogenous exposure relation found for postmenopausal exposed women is consistent with data on male smelter workers, whereas the relation found for premenopausal women is significantly lower. This suggests that sex plays an important role in the metabolism of lead, and current models of exposure extrapolated from male data may be inappropriate for use on women.

 

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