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Greenlist(tm) Bulletin 08/19/2005


This is the weekly bulletin of the TURI Library, reporting a selection of recently published titles we have acquired. Our pledge is to keep the bulletin relevant to your work and brief -- no more than 10 titles. You are welcome to send a message to jan@turi.org if you would like more information on any of the articles listed here.


Titles here, abstracts below them:
  1. Better Bonding with Beans. August 2005
  2. Investigating the Possible Health Hazards of Nanoparticles. July 2005
  3. EU's Volatile Organic Compound Emissions Directive and the Switch to Silicones. May 2005
  4. Korea to Ban Phthalates in Toys. August 2005
  5. The Clock is Ticking. June 2005

 


1. Better Bonding with Beans

AUTHOR Brown, Valerie J.

DATE 2005

SOURCE Environmental Health Perspectives, v113 n8, August 2005, ppA539-541

ABSTRACT Formaldehyde is an extremely useful industrial chemical but also one that has long been known to cause environmental health problems in some circumstances. A major route for human exposure is inhalation of formaldehyde gas emitted from urea- and phenol-formaldehyde resins used as adhesives in engineered woods such as plywood and particleboard. Industrial workers are exposed to significantly higher amounts of formaldehyde than the general public, although residents of new homes built with engineered wood materials often experience symptoms, especially soon after moving in. Formaldehyde concentrates in indoor air, with known and suspected human health effects ranging from eye irritation to cancer. Now a new adhesive using soy protein, processed to resemble the protein that allows mussels to cling to rocks, is enabling some manufacturers to make formaldehyde-free engineered woods. Developed by Kaichang Li, an associate professor in the wood science and engineering department at Oregon State University in Corvallis, the soy adhesive is being hailed by many as a nontoxic, economically attractive, and renewable solution to a long-standing environmental health issue. Li’s new soy adhesive is an ingenious chemical construct, something of a Holy Grail in the search to make vegetable proteins that are strong enough and water-resistant enough to hold up in industrial applications. In a report published in the September 2002 issue of Macromolecular Rapid Communications, Li noted the fine complementarity between the features of marine adhesive proteins (like those that make clinging mussels such a threat to boat hulls) and soy proteins. Marine adhesive proteins stick to wet and irregular surfaces, bind very strongly, and degrade very little, but are burdensome and costly to synthesize; soy proteins are abundant, renewable, and affordable, but are relatively weak and easily degraded. Li was able to get the best of both worlds by coaxing soy protein to cross-link with the adhesive’s second major ingredient— a proprietary resin known as kymene—in a similar manner to mussel adhesive. Cross-linking organizes large molecules into a mesh-like configuration. In Li’s soy adhesive, this occurs after the glue is applied to the wood, during curing (the chemical and physical process by which ingredients are united into a stable form). The cross-links in Li’s adhesive are so strong that it can be boiled for hours without degrading, he says.


2. Investigating the Possible Health Hazards of Nanoparticles

DATE 2005

SOURCE Chemical Engineering, v112, n7, July 2005, p17

ABSTRACT Establsihing processes to detect, track and characterize nanoparticles is the key goal of a European research project. With scientists from industry, startup firms and research institutions from seven EU countries, the 23 partners in the project will look at the entire lifecycle of nanoparticles, from their production and storage through transport and use in final products.


3. EU's Volatile Organic Compound Emissions Directive and the Switch to Silicones

AUTHOR Reinders, Roger; Gubbels, Frederic; Dandois, Robert

DATE 2005

SOURCE Global SMT & Packaging, v5 n5, May 2005, pp10-13, 18

ABSTRACT Within our industrial society increased attention is devoted to pollution prevention. This article focuses on the Volatile Organic Compound Emissions Directive (1999/13/EC), and discusses what that document means for European companies consuming conformal coatings and solder fluxes. The article offers a calculation tool and example calculations that can determine whether or not a manufacturing plant that is using conformal coatings is in line with the Volatile Organic Compound Emissions Directive. Also, practical and effective solutions to comply with the directive are discussed.

 


4. Korea to Ban Phthalates in Toys

AUTHOR Young, Ian

 

DATE 2005

SOURCE Chemical Week, v167 n25, August 3, 2005, p15

ABSTRACT The Korean government says it intends to ban the use of phthalate plasticizers in toys and other children's products, on safety grounds. The ban would start next year, according to the Korean Agency for Technology and Standards (Seoul), a state-run body.


5. The Clock is Ticking

AUTHOR Carbone, James

DATE 2005

SOURCE Purchasing, June 16, 2005, p28

ABSTRACT Time is running out for electronics companies to meet European Union's ban on the use of lead and five other hazardous substances in equipment sold in Europe. The Restriction on the Use of Hazardous Substances (RoHS) law requires that beginning in July 2006 electronics equipment sold in Europe, with some exceptions, must be free of lead, mercury, cadmium, chromium, polybrominated biphenyls, and polybrominated diphenyl ethers. The ban is having a huge impact on the electronics industry and on purchasers at OEM and electronics manufacturing services (EMS) providers. Companies are substituting parts and changing manufacturing processes and buyers are monitoring which suppliers are making RoHS-compliant parts. By some estimates, only about 25% of electronics suppliers are currently producing parts that are RoHS compliant. One reason many are not yet compliant is cost. Companies in the electronics supply chain will spend between $5-10 billion collectively to comply with the legislation, according to industry analysts. Of the six banned substances, lead is the most widely used in the electronics industry. It is in solder to connect parts to boards and in the plating of parts. Companies are spending millions of dollars in finding lead-free alternatives and manufacturing processes to handle the lead-free parts. The good news for buyers is that most major semiconductor suppliers have converted at least some parts to lead-free or are in the process of doing so and have settled on lead-free alternatives. For instance, with reflow solder, many suppliers plan to use silver-tin copper rather than tin lead, although there are a host of other alternatives including tin bismuth, indium silver and tin zinc among others. In semiconductors, lead has been used in a compound for lead frames, package leads and printed-circuitboard tabs. Some chip companies like Samsung will use a lead-free compound of tin bismuth and silver. Texas Instruments is using nickel-palladium gold finish in its leadframes for logic parts. With connectors, many manufacturers are using tin-over-nickel plating rather than lead-based plating.

 

You are welcome to send a message to jan@turi.org if you would like more information on any of these resources. Also, please tell us what topics you are particularly interested in monitoring, and who else should see GREENLIST. An online search of the TURI Library catalog can be done at http://greenlist.turi.org/ for greater topic coverage.

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