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Greenlist(tm) Bulletin 10/07/2005


This is the weekly bulletin of the TURI Library, reporting a selection of recently published titles we have acquired. Our pledge is to keep the bulletin relevant to your work and brief -- no more than 10 titles. You are welcome to send a message to jan@turi.org if you would like more information on any of the articles listed here.

Titles here, abstracts below them:
  1. Lead Contamination in Cocoa and Cocoa Products: Isotopic Evidence of Global Contamination. October 2005
  2. Significance of intermediate production processes in life cycle assessment of electronic products assessed using a generic compact model. November 2005
  3. Socma Replaces Responsible Care. September 2005
  4. Seeking Citizens' Views on GM Crops: Experiences from the United Kingdom, Australia, and New Zealand. September 2005
  5. Rating System for Pilot Demonstration of LEED(r) for Homes Program. September 2005
  6. Most Hospitals Eliminating Mercury, National Survey Finds. September 2005
  7. Association between occupational exposure to mineral oil and rheumatoid arthritis: results from the Swedish EIRA case–control study. September 2005
  8. Three Keys to Optimizing Solvent Blends. September 2005
  9. Relative Risk Analysis of Several Manufactured Nanomaterials: An Insurance Industry Context. October 2005
  10. Precision Bonding Makes Tiny High Performance Actuators Possible. October 2005

 

 


1. Lead Contamination in Cocoa and Cocoa Products: Isotopic Evidence of Global Contamination

AUTHOR Rankin,Charley W. ; Nriagu, Jerome O.; Aggarwal, Jugdeep K.; Arowolo, Toyin A.; Adebayo, Kola; Flegal, A. Russell

DATE 2005

SOURCE Environmental Health Perspectives, v113 n10, October 2005, pp1344-1348

ABSTRACT In this article we present lead concentrations and isotopic compositions from analyses of cocoa beans, their shells, and soils from six Nigerian cocoa farms, and analyses of manufactured cocoa and chocolate products. The average lead concentration of cocoa beans was = 0.5 ng/g, which is one of the lowest reported values for a natural food. In contrast, lead concentrations of manufactured cocoa and chocolate products were as high as 230 and 70 ng/g, respectively, which are consistent with market-basket surveys that have repeatedly listed lead concentrations in chocolate products among the highest reported for all foods. One source of contamination of the finished products is tentatively attributed to atmospheric emissions of leaded gasoline, which is still being used in Nigeria. Because of the high capacity of cocoa bean shells to adsorb lead, contamination from leaded gasoline emissions may occur during the fermentation and sun-drying of unshelled beans at cocoa farms. This mechanism is supported by similarities in lead isotopic compositions of cocoa bean shells from the different farms (206Pb/207Pb = 1.1548–1.1581; 208Pb/207Pb = 2.4344–2.4394) with those of finished cocoa products (206Pb/207Pb = 1.1475–1.1977; 208Pb/207Pb = 2.4234–2.4673). However, the much higher lead concentrations and larger variability in lead isotopic composition of finished cocoa products, which falls within the global range of industrial lead aerosols, indicate that most contamination occurs during shipping and/or processing of the cocoa beans and the manufacture of cocoa and chocolate products.


2. Significance of intermediate production processes in life cycle assessment of electronic products assessed using a generic compact model

AUTHOR Andrae, Anders S.g.; Andersson, Dag R.; Liu, Johan

SOURCE Journal of Cleaner Production, v13 n13-14, November-December 2005, pp1269-1279

ABSTRACT In this paper a generic model for life cycle inventory (LCI) data collection is presented and applied to a product system of a Digital System Telephone (DST). It is shown that the intermediate unit processes (IUPs) are of global warming importance. Compared to earlier efforts in the field of environmental life cycle assessment of electronic products, this model enables a more partitioned LCA result, with respect to both components and processes. In our model the components are first divided into main groups and then into sub-groups. This division results in process modules for unit processes, some of which are similar to the ongoing components, thus, reducing the computational effort. The model is demonstrated for a ‘‘cradle-to-gate’’ calculation focusing on greenhouse gas emissions. Using scenario analysis for integrated circuits and printed wiring boards, the possible contribution from IUPs was analysed.


3. Socma Replaces Responsible Care

AUTHOR Kamalick, Joe

SOURCE Chemical Market Reporter, v268 n9, 19-25 September, 2005, p8

ABSTRACT The Synthetic Organic Chemical Manufacturers Association (Socma) said last week that it is replacing the Responsible Care environmental and safety program with a program of its own called ChemStewards. Socma president Joseph Acker said Socma will end its licence agreement for Responsible Care at the end of this month. Responsible Care is owned by the American Chemistry Council (ACC) and is licensed to other industry groups. Acker said Socma developed ChemStewards over the last year in response to member company demands for an environmental, health, safety and security (EHS&S) program that “is more flexible and not a one-size-fits-all approach.”


4. Seeking Citizens' Views on GM Crops: Experiences from the United Kingdom, Australia, and New Zealand

AUTHOR Walls, John; Rogers-Hayden, Tee; Mohr, Alison; O'Riordan, Timothy

SOURCE Environment, v47 n7, September 2005, pp22-36

ABSTRACT Over the past decade or so, there have been intense public discussions about whether to permit the commercial planting of genetically modified (GM) crops in a number of developed and to a lesser extent, developing countries. In the European Union (EU) this debate led to a five-year moratorium (voluntarily agreed to by industry and government) on the introduction of commercial GM crops from 1999 to 2004. Even at the end of this period, regulations are extraordinarily tight, and GM companies have yet to fully enter the EU market. In the United States, the largest producer of GM crops, there has been virtually no organized public opposition. This long-running dispute also raises the issue of how the scientific community evaluates the safety of GM crops and foods and how various countries decides the extent to which they will invoke the precautionary principle. The procedures through which such decisions are being made invoke a variety of citizen-based deliberative approaches. Beginning with Australia in the late 1990s, the United Kingdom, Australia, and New Zealand each conducted such processes with the ostensive goal of incorporating a wider public appraisal of the scientific evidence. Examining the experiences of these three nations are particularly useful for comparing varying approaches to public deliberation, as they all took a different format. In addition, although the political and cultural circumstances of the three case studies differed, the manner of handling these opportunities were surprisingly similar.


5. Rating System for Pilot Demonstration of LEED(r) for Homes Program

DATE 2005

SOURCE U.S. Green Building Council

ABSTRACT USGBC has established Leadership in Energy and Environmental Design (LEED) as a recognized national green building rating system in the US. LEED for Homes is a voluntary initiative designed to actively promote the transformation of the mainstream home building industry towards more sustainable practices. LEED for Homes aims to recognize the top 25 percent of homes which incorporate best-practice environmental features, including: 1. The efficient use of energy resources; 2. The efficient use of water resources;3. The efficient use of building construction resources (i.e., through improved design, material selection and utilization, and construction practices), 4. The efficient use of land resources, and 5. Enhanced indoor environmental quality to safeguard the health of the home’s occupants. LEED for Homes will rate qualified homes at the certified, silver, gold and platinum levels, in recognition of the level of performance achieved in each of the above five resource categories. The objective of pilot testing LEED for Homes is to ensure the LEED for Homes rating system is practical for application and will become an effective tool for introducing green building practices to a significant portion of the new home building marketplace. The pilot is planned for August 5005 thru early 2007.


6. Most Hospitals Eliminating Mercury, National Survey Finds

DATE 2005

SOURCE GreenBiz.com, accessed September 30, 2005

ABSTRACT Hospitals have significantly reduced the amount of mercury found in facilities and are demonstrating a clear preference for safer alternatives, according to a recent national survey by the American Hospital Association (AHA) and Hospitals for a Healthy Environment (H2E). Survey highlights:* 97% of hospital respondents across the country were aware of the problem with mercury and had taken steps to address the issue, including labeling mercury-containing devices and phasing out their purchase in favor of safer, equally effective alternatives;* 80% of respondents had completely eliminated the use of mercury fever thermometers;* 73% had removed all mercury sphygmomanometers from their facilities, more than 81% currently purchase mercury-free cleaning chemicals, and 64% purchase mercury-free pharmaceuticals;* 60% of respondents had implemented a mercury management policy, and more than 54% had established a policy to virtually eliminate mercury facility-wide. "More than 1,000 hospitals across the U.S. have pledged to virtually eliminate mercury medical devices. More than 90% of pharmacy chains have stopped selling mercury fever thermometers. Three of the five largest health care group purchasing organizations now have mercury-free purchasing policies. This survey reveals a deep shift in the culture of the industry," said Laura Brannen, executive director of Hospitals for a Healthy Environment. "Hospitals have recognized that they shouldn't be contributing to the serious public health threat caused by mercury pollution. We now have the opportunity to build on the tremendous work that's been accomplished to finish eliminating mercury from the delivery of health care, making it safer and healthier for all of us."


7. Association between occupational exposure to mineral oil and rheumatoid arthritis: results from the Swedish EIRA case–control study

AUTHOR Sverdrup, Berit; Kallberg, Henrik; Bengtsson, Camilla; Lundberg, Ingvar; Padyukov, Leonid; et al.

SOURCE Arthritis Research & Therapy, 7:R1296-R1303, September 2005

ABSTRACT The aim of the present study was to investigate the association between exposure to mineral oil and the risk of developing rheumatoid arthritis (RA), and in addition to perform a separate analysis on the major subphenotypes for the disease; namely, rheumatoid factor (RF)-positive RA, RF-negative RA, anticitrulline-positive RA and anticitrulline-negative RA, respectively. A population-based case–control study of incident cases of RA was performed among the population aged 18–70 years in a defined area of Sweden during May 1996–December 2003. A case was defined as an individual from the study base who for the first time received a diagnosis of RA according to the American College of Rheumatology criteria of 1987. Controls were randomly selected from the study base with consideration taken for age, gender and residential area. Cases (n = 1,419) and controls (n = 1,674) answered an extensive questionnaire regarding lifestyle factors and occupational exposures, including different types of mineral oils. Sera from cases and controls were investigated for RF and anticitrulline antibodies. Among men, exposure to any mineral oil was associated with a 30% increased relative risk of developing RA (relative risk = 1.3, 95% confidence interval = 1.0–1.7). When cases were subdivided into RF-positive RA and RF-negative RA, an increased risk was only observed for RF-positive RA (relative risk = 1.4, 95% confidence interval 1.0–2.0). When RA cases were subdivided according to the presence of anticitrulline antibodies, an increased risk associated with exposure to any mineral oil was observed only for anticitrulline-positive RA (relative risk = 1.6, 95% confidence interval = 1.1–2.2). Analysis of the interaction between oil exposure and the presence of HLA-DR shared epitope genes regarding the incidence of RA indicated that the increased risk associated with exposure to mineral oil was not related to the presence of shared epitope genotypes. In conclusion, our study shows that exposure to mineral oil is associated with an increased risk to develop RF-positive RA and anticitrulline-positive RA, respectively. The findings are of particular interest since the same mineral oils can induce polyarthritis in rats.


8. Three Keys to Optimizing Solvent Blends

AUTHOR Anderson, Ranae

SOURCE PCI Paint & Coatings Industry, v21 n9, September 2005, pp92-94

ABSTRACT A variety of coating technologies exist in the marketplace today, with solventborne technologies still preferred for many high-performance applications. As government regulations affecting the coatings industry have become more stringent and complex, today’s formulators have become more aware of the importance of optimizing their solvent blend to achieve the desired balance between regulatory compliance and film properties. This article discusses three solvent properties that are critical to developing or reformulating a solvent blend — solubility parameters, evaporation rate and escape coefficients.


9. Relative Risk Analysis of Several Manufactured Nanomaterials: An Insurance Industry Context

AUTHOR Robichaud, Christine Ogilvie; Tanzil, Dicksen; Weilenmann, Ulrich; Wiesner, Mark

SOURCE Environmental Science & Technology, online pre-print, October 4, 2005

ABSTRACT A relative risk assessment is presented for the industrial fabrication of several nanomaterials. The production processes for five nanomaterials were selected for this analysis, based on their current or near-term potential for large-scale production and commercialization: singlewalled carbon nanotubes, bucky balls (C60), one variety of quantum dots, alumoxane nanoparticles, and nanotitanium dioxide. The assessment focused on the activities surrounding the fabrication of nanomaterials, exclusive of any impacts or risks with the nanomaterials themselves. A representative synthesis method was selected for each nanomaterial based on its potential for scaleup. A list of input materials, output materials, and waste streams for each step of fabrication was developed and entered into a database that included key process characteristics such as temperature and pressure. The physicalchemical properties and quantities of the inventoried materials were used to assess relative risk based on factors such as volatility, carcinogenicity, flammability, toxicity, and persistence. These factors were first used to qualitatively rank risk, then combined using an actuarial protocol developed by the insurance industry for the purpose of calculating insurance premiums for chemical manufacturers. This protocol ranks three categories of risk relative to a 100 point scale (where 100 represents maximum risk): incident risk, normal operations risk, and latent contamination risk. Results from this analysis determined that relative environmental risk from manufacturing each of these five materials was comparatively low in relation to other common industrial manufacturing processes. 


10. Precision Bonding Makes Tiny High Performance Actuators Possible

DATE 2005

SOURCE Pennsylvania State University

ABSTRACT Using a new precision bonding process they developed, Penn State researchers have designed and fabricated tiny new piezoelectric microactuators – the largest only a hair’s breadth wide -- based on coupling commercially available materials with existing micromachining technology. The new actuators promise to be low cost and capable of providing controlled force, high resolution and large displacements appropriate for applications in RF switches for cell phones, for example, or optical switches for wide screen TVs. Other potential applications include microfluidic pumps and valves, micromanipulators for nanoscale handling and atomic force microscope drives. Dr. Srinivas A. Tadigadapa, associate professor of electrical engineering and a developer of the bonding process and microactuator, says, "These new piezoelectric microactuators are the first realized using microfabrication methods, a mature technology used to make computer chips and micromachines from silicon-based materials. Our new low temperature wafer bonding techniques, which make the actuators possible, can also be used for precision integration of dissimilar materials in other micro-electro-mechanical systems." The new actuators are made from flat strips of bulk PZT, a commercially available piezoelectric material that shrinks slightly when a voltage is applied to it, and a precision micromachined silicon beam. Bonding the silicon beam to the PZT amplifies and converts the PZT shape change into a convex deflection when the silicon beam buckles as the PZT shrinks.

 

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