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Greenlist(tm) Bulletin 11/12/04


Greenlist(tm) Bulletin 11/12/04

This is the weekly bulletin of the TURI Library, reporting a selection of recently published titles we have acquired. Our pledge is to keep the bulletin relevant to your work and brief -- no more than 10 titles. (usually)
Titles here, abstracts below them:
  1. EMS Accomplishments Through the Pollution Prevention Program, November 2004
  2. Industry, Activists Spar Over Bush EPA Enforcement, October 2004
  3. Green Chemistry, October/November 2004
  4. The Best of Both Worlds, Case Study: The Auto Industry and Better Cleaning Processes, October 2004
  5. Improved Productivity for Cable Manufacture, October 2004
  6. Foam Protects: Intumescent Coatings and Paints for Fire Protection, October 2004
  7. A Comparative Study of Water-Borne Coatings for Metal Protection, October 2004
  8. Just One Word: Carbohydrates - Chemical and Energy Companies Take on the Petroleum Habit, September 2004
  9. Toxic Iodoacid By-Products of Clean Water, September 2004
  10. Sustainable Coatings Approach Total Coverage, March 2004
1. TITLE EMS Accomplishments Through the Pollution Prevention Program
AUTHOR Mauer Sculthorpe, Katherine
SOURCE Metal Finishing, November 2004, vol. 102, no. 11, pp. 35-38
ABSTRACT Eglin's Environmental Management Systems (EMS) is successful at identifying high-risk process groups and reducing risk by decreasing hazardous materials (HAZMAT) usage, air emissions, and hazardous waste (HW) generation. It also has proven to increase shop efficiencies and worker safety through compliance site inventory (CSI) and process specific opportunity assessment (PSOA) processes. As part of the EMS process, Eglin AFB has developed a CSI listing of more than 3,000 aspects specifically related to activities and processes that have an environmental impact and are subject to specific regulatory requirements. Eglin is expanding CSI to be a true environmental aspects inventory (EAI), which would contain all cultural and natural resources, biological health, safety, noise, infrastructure, community concerns, and any other data that might have or be an environmental impact. Examples of existing compliance sites include range road and stream crossings, hazardous waste storage and collection containers, air pollution emission sources like boilers or paint booths, or HAZMAT storage areas.

Compliance sites are grouped and then ranked by environmental, health, and mission impact/risk. PSOAs are scheduled at top-ranking shops and used to develop potential solutions in the most cost-effective and environmentally sound manner. Eglin has found the PSOA process to be instrumental in soliciting an environmental initiative from the shop level and therefore garnering greater continued environmental support. The CSI and PSOA Web sites contain a searchable on-line inventory of compliance sites and potential environmental opportunities for shop review. The opportunities implementation can additionally be tracked through the Web site.


2. TITLE Industry, Activists Spar Over Bush EPA Enforcement
AUTHOR Sissell, Kara
SOURCE Chemical Week, October 20, 2004, vol. 166, no. 34, p. 61
ABSTRACT The Environmental Integrity Project has released a report that says EPA's environmental enforcement actions have decreased 75% since President Bush took office, a claim industry denies. EIP is headed by Eric Schaeffer, a former enforcement chief at EPA who quit in 2002 to protest the agency's proposed overhaul of the New Source Review rule.


3. TITLE Green Chemistry
AUTHOR Warner, John C.; Cannon, Amy S.; Dye, Kevin M.
SOURCE Environmental Impact Assessment Review, October/November 2004, vol. 24, nos. 7-8, pp. 775-799
ABSTRACT A grand challenge facing government, industry, and academia in the relationship of our technological society to the environment is reinventing the use of materials. To address this challenge, collaboration from an interdisciplinary group of stakeholders will be necessary. Traditionally, the approach to risk management of materials and chemicals has been through interventions intended to reduce exposure to materials that are hazardous to health and the environment. In 1990, the Pollution Prevention Act encouraged a new tact - elimination of hazards at the source. An emerging approach to this grand challenge seeks to embed the diverse set of environmental perspectives and interests in the everyday practice of the people most responsible for using and creating new materials—chemists. The approach, which has come to be known as Green Chemistry, intends to eliminate intrinsic hazard itself, rather than focusing on reducing risk by minimizing exposure. This chapter addresses the representation of downstream environmental stakeholder interests in the upstream everyday practice that is reinventing chemistry and its material inputs, products, and waste as described in the ‘‘12 Principles of Green Chemistry’’.


4. TITLE The Best of Both Worlds, Case Study: The Auto Industry and Better Cleaning Processes
AUTHOR Green, Newton B.; Herrington, Philip
SOURCE Clean Tech, October 2004, vol. 4, no. 10, pp. 31-33
ABSTRACT The National center for Remanufacturing and Resource Recovery (NCR3) at the Rochester Institute of Technology seeks to assist manufacturing companies and remanufacturing companies to improve productivity while reducing their impact on the environment. A particularly critical aspect of remanufacturing is surface cleaning, which can represent a large portion of the cost of remanufacturing a product. Alternative cleaning systems can be identified through a process known as a cleaning assessment, which will be described.


5. TITLE Improved Productivity for Cable Manufacture
SOURCE Plastics Engineering, October 2004, vol. 60, no. 10, p. 8
ABSTRACT To help satisfy the growing demand for MV (megavolt), HV (high voltage), and EHV (extra high voltage) underground cable systems for electric energy transmission, Borealis, a supplier of polyethylene to the wire and cable industry, has developed Supercure LS4201. The XLPE (crosslinked polyethylene) compound can effect significant increases in cable production speed without sacrificing quality or performance, says the company. Supercure LS4201, a further development of Borealis' LE4201, was engineered to enhance performance by decreasing the length of the processing run (thus lower propensity for scorch), by reducing the degassing process, and by maintaining or increasing extrusion speed. Degassing is an important process for HV and EHV cables because it removes the crosslinking by-products (e.g. methane) that would result in a number of problems if left within the XLPE matrix. The time required to degas cable primarily depends on the initial level of by-products. Traditionally, the process has been accelerated by increasing the temperature, which speeds up degassing but also uses significant amounts of energy and can cause damage to the cable core. Supercure LS4201 reduces the degassing requirements and thus can significantly improve cable productivity, says Borealis. The scale of productivity improvements that can accrue from the increased throughput offered by Supercure LS4201 (increased length of run at essentially identical line speeds) depends on cable design, size, and manufacturing principles. For example, at 12-mm wall thickness, production time can be reduced by 25% or more, reports the company. www.borealisgroup.com


6. TITLE Foam Protects: Intumescent Coatings and Paints for Fire Protection
AUTHOR Walz, Rudiger; Thewes, Volker
SOURCE Paint & Coatings Industry, October 2004, vol. 20, no. 10, pp. 148-152
ABSTRACT Fires are devastating and, unfortunately, occur all too frequently. The estimated annual cost to the economy of fire damage is $400 billion, i.e., around one percent of world GNP literally goes up in smoke. One reason is the high flammability of many materials such as wood, textiles ad plastics used in clothing and furnishings, etc. Suitable flame retardants are required for most of these materials if they are to be used in high-fire-risk areas. However, it is not always possible to add flame retardants as additives to raw materials. In some cases, the substrate is incompatible with further additives; in others the desired flammability rating cannot be achieved with a single additive, or the use of a flame-retardant product is simply too expensive. Frequently, the solution then lies in "intumescent coatings: - a sure method with great potential, as the following article shows.

7. TITLE A Comparative Study of Water-Borne Coatings for Metal Protection
AUTHOR Mestach, D.; Weber, M.; Goossen, J.; van de Watering, P.
SOURCE Journal of Protective Coatings & Linings, Vol. 21, No. 10, October, 2004, pp. 32-38
ABSTRACT In the shop coating metal protection market, the dominant technology in Europe is still either solvent-borne two-component (2K) urethanes or one-component (1K) solvent-borne alkyds. Faced with the upcoming European legislation on volatile organic compounds (VOCs), paint manufacturers are being forced to switch from conventional solvent- borne coatings to VOC-compliant technologies. In this respect, water-borne resin technology plays an important role in replacing solvent-borne coatings. The progress made over the years in the design of water-borne polymers has enabled us to overcome the drawbacks that were associated with the first generation of water-borne binders. In addition to reducing VOC emissions during application, water-borne coatings reduce the risk of fire, are easier to clean up (creating less hazardous residue), and result in reduced worker exposure to organic vapors. Finally, the use of water-borne technology might reduce overall costs for the coating process. The growing acceptance of water-borne binders in the metal coatings market was the reason for the comparative study described in this article. Different existing water-borne resin technologies, both 1K and 2K, are the focus. This article discusses testing carried out and comment son the economics of water-borne coatings.


8. TITLE Just One Word: Carbohydrates - Chemical and Energy Companies Take on the Petroleum Habit
AUTHOR Boswell, Clay
SOURCE Chemical Market Reporter, Vol. 266, No. 8, September 13, 2004, p. FR12, FR14
ABSTRACT There is only so much petroleum in the earth, and as time passes, that oil will become increasingly rare, petrochemicals will become specialties, and chemical manufacturing will turn to carbohydrate feedstocks. The transformation is already in progress. The production of glucose from corn has evolved to a highly efficient process, and tremendous advances have been made in the economical production of carbohydrates from non-traditional sources such as wood and agricultural waste. Using recombinant technologies, researchers have adapted microorganisms to produce a range of basic chemicals from carbohydrates, and companies such as Cargill Inc., Dow Chemical and DuPont have begun the development of a platform of biobased chemicals that will open the door to a new era of chemical innovation and long-term sustainability.

9. TITLE Toxic Iodoacid By-Products of Clean Water
SOURCE Chemical & Engineering News, September 20, 2004, vol. 82, no. 38, p. 40
ABSTRACT A new class of highly toxic contaminants has shown up among the disinfection by-products of a Texas drinking water treatment plant. Iodoacids (including iodoacetic acid and some brominated compounds such as 3-bromo-3-iodopropenoic acid) are the likely result of a pair of reactions. A chloramine disinfectant reacts with iodide (which seeps into the Texas water from an ancient seabed) to form HOI, and HOI reacts with natural organic matter to form a variety of iodoacids. Michael J. Plewa of the University of Illinois, Urbana-Champaign, and coworkers tested iodoacetic acid for its biological toxicity. "Iodoacetic acid is the most potent cytotoxic and genotoxic disinfection by-product that I have ever seen in mammalian cells, "Plewa reports. He suspects that only treatment plants that rely solely on chloramination disinfection and encounter high levels of iodide and bromide should produce the iodoacids. He adds that his data highlight the dangers of not having a comparative database of disinfection by-products.

10. TITLE Sustainable Coatings Approach Total Coverage
SOURCE Architecture, March 2004, vol. 93, issue 3, p. 77-
ABSTRACT Features several low volatile organic compound products with E3 ratings that have met the requirements of international green standards. Hydropox No. 2 epoxy from Griggs Paint; Old Masters H2O acrylic varnish from Diamond Vogel; EcoLogic lacquer from Cloverdale Paint; Morwear Floor & Patio floor paint from Smiland Paint.

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