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Greenlist(tm) Bulletin 01/13/2006


This is the weekly bulletin of the TURI Library, reporting a selection of recently published titles we have acquired. Our pledge is to keep the bulletin relevant to your work and brief -- no more than 10 titles. You are welcome to send a message to jan@turi.org if you would like more information on any of the articles listed here.

Titles here, abstracts below them:
  1. Mazda, Nippon Paint Develop Eco-friendly Coating Process
  2. Tiny crystals promise big benefits for solar technologies
  3. Canada contemplates restrictions on well-loved stain repellents
  4. Household Consumption and the Environment
  5. Shiitake Mushrooms' Secret May Benefit Earth-Friendly Fuels
  6. Assessing the Reliability and Credibility of Industry Science and Scientists
  7. Biopesticides growing strong
  8. Concentrations of surface-dust metals in Native American jewelry-making homes in Zuni Pueblo, New Mexico
  9. Additives Annual: Enhancing Performance, Versatility and Processability of Polymers
  10. Toxic at Any Speed: Chemicals in Cars and the Need for Safer Alternatives

1. Mazda, Nippon Paint Develop Eco-friendly Coating Process

SOURCE Japan for Sustainability, www.japanfs.org, November 30, 2005

ABSTRACT An electro-deposition basecoat known as e-coating that substantially reduces both volatile organic compounds (VOCs) and carbon dioxide (CO2) emissions has been developed by Mazda Motor Corp., a major Japanese automaker, in collaboration with Nippon Paint Co. Mazda had already developed a "Three-Layer Wet Paint System" that combined the primer, base and clear coats into one painting process, and introduced it to all its plants in Japan. The new e-coating developed at this time significantly reduces environment-impacting substances included for rust protection in the base coat process. In the electro-deposition painting process, the vehicle body is immersed in a paint tank and an electric current is passed through its steel parts, causing the paint adhere to the steel surfaces. With conventional paints, electrical currents pass through some parts more easily than others, causing discrepancies in paint film thickness between the inside and outside body surfaces. As a result, excess paint adhered to the outside body surface while the inside body surface was insufficiently coated. The newly developed e-coating has reduced the viscosity of the paint and raised its electrical resistance, reducing the amount of electricity used during painting. This provides sufficient paint thickness on inside surfaces and increases rust protection, while excess paint accumulated on outer surfaces can be adjusted to an appropriate level, allowing also for a reduction in total paint consumption. Mazda plans to introduce this new paint to its four plants in Japan within the year. This will reduce VOC emissions during basecoat painting by 32 tons, CO2 emissions during paint manufacture by 8.8 tons per year and the volume of basecoat materials by more than 10 percent compared to previous methods, the company said.


2. Tiny crystals promise big benefits for solar technologies

SOURCE Los Alamos National Laboratory, www.lanl.gov, Accessed January 12, 2006

ABSTRACT Los Alamos National Laboratory scientists have discovered that a phenomenon called carrier multiplication, in which semiconductor nanocrystals respond to photons by producing multiple electrons, is applicable to a broader array of materials that previously thought. The discovery increases the potential for the use of nanoscrystals as solar cell materials to produce higher electrical outputs than current solar cells. In papers published recently in the journals Nature Physics and Applied Physics Letters, the scientists demonstrate that carrier multiplication is not unique to lead selenide nanocrystals, but also occurs with very high efficiency in nanocrystals of other compositions, such as cadmium selenide. In addition, these new results shed light on the mechanism for carrier multiplication, which likely occurs via the instantaneous photoexcitation of multiple electrons. Such a process has never been observed in macroscopic materials and it explicitly relies on the unique physics of the nanoscale size regime. The Los Alamos findings point toward practical photovoltaic technologies that may utilize such traditional solar cell materials as cadmium telluride, which is very similar to cadmium selenide. Other interesting opportunities may also be associated with the use of carrier multiplication in solar-fuel technologies and specifically, the production of hydrogen by photo-catalytic water splitting. The latter process requires four electrons per water molecule and its efficiency can be dramatically enhanced if these multiple electrons can be produced via a single-photon absorption event.


3. Canada contemplates restrictions on well-loved stain repellents

 

AUTHOR Renner, Rebecca

SOURCE Environmental Science & Technology Online News, January 11, 2006

ABSTRACT Widely used stain repellants that keep fast-food grease off clothes and nasty stains off carpets could be on their way out in Canada, given two recent actions. Last December, the country announced its intention to craft a plan to evaluate, regulate, restrict, or ban the entire class of chemical compounds known as fluorotelomer polymers and their precursors. Officials with Environment Canada (EC), the country’s environmental regulator, say that they believe fluorotelomer polymers contribute to widespread environmental contamination by perfluorocarboxylates (PFCAs), which are persistent and bioaccumulative and have been linked to cancer and developmental effects in animal experiments. EC also notes that the properties of PFCAs with long chains (carbon–fluorine chains that contain nine or more carbons) meet the criteria for persistent organic pollutants (POPs) under the international Stockholm Convention on Persistent Organic Pollutants.


4. Household Consumption and the Environment

SOURCE European Environment Agency

DATE 2005

ABSTRACT A renewed policy focus on sustainable consumption and production (SCP) can be observed, both at the global level and in Europe. With an aim to provide input for European policy-making, this report analyses the environmental effects of household consumption in Europe. We have identified four consumption categories that form a major part of our total consumption expenditure and for which the environmental effects are either large or increasing rapidly. These are consumption of food and drink; housing; personal travel and mobility; and tourism. The negative environmental effects of our consumption do not only occur in Europe, but also in other regions of the world, mainly as a result of resource extraction, production, processing and transportation of the goods we consume in Europe, and as a result of our personal travel and tourist activities. Attaining more sustainable consumption and production patterns is a common challenge that involves all actors, including public authorities at all levels, business and consumers.


5. Shiitake Mushrooms' Secret May Benefit Earth-Friendly Fuels

AUTHOR Wood, Marcia

SOURCE Agricultural Research Service, http://www.ars.usda.gov, November 29, 2005

ABSTRACT Fallen logs on the forest floor make a perfect home for Shiitake mushrooms. These fungi--sold as a delicacy in the produce section of your local supermarket--thrive on the downed wood, turning it into sugars that they use for food. Now, Agricultural Research Service scientists in California are looking at bringing the gourmet mushrooms' mostly unstudied talent indoors. And, as a first step towards doing that, they've found and copied a Shiitake gene that's key to the mushroom's ability to dissolve wood. Called Xyn11A, the gene carries the instructions that the mushroom uses to make an enzyme known as xylanase. The researchers want to see if a ramped-up version of the gene could be put to work digesting rice hulls or other harvest leftovers. If enzymes can do that quickly and efficiently in huge vats, or fermenters, at biorefineries, they could help make ethanol and other products a practical alternative to today’s petroleum-based fuels, for example. In laboratory experiments, Agricultural Research Service scientists transferred the Xyn11A gene into yeast. Equipped with the gene, the yeast was able to produce xylanase. In nature, the yeast normally can’t do that. Next, the scientists will work on engineering the mushroom gene so that it enables yeast or some other organism to produce greater amounts of the xylanase enzyme in less time. Gains in efficiency could help make biorefining of plant-based fuels and other products a practical alternative to petroleum refining.


6. Assessing the Reliability and Credibility of Industry Science and Scientists

AUTHOR Barrow, Craig S.; Conrad, James W., Jr.

SOURCE Environmental Health Perspectives, v114 n2, February 2006, pp153-155

ABSTRACT The chemical industry extensively researches and tests its products to implement product stewardship commitments and to ensure compliance with governmental requirements. In this commentary we argue that a wide variety of mechanisms enable policymakers and the public to assure themselves that studies performed or funded by industry are identified as such, meet high scientific standards, and are not suppressed when their findings are adverse to industry’s interests. The more a given study follows these practices and standards, the more confidence one can place in it. No federal laws, rules, or policies express a presumption that scientific work should be ignored or given lesser weight because of the source of its funding. To the contrary, Congress has consistently mandated that agencies allow interested or affected parties to provide information to them and fairly consider that information. All participants in scientific review panels should disclose sources of potential biases and conflicts of interest. The former should be considered in seeking a balanced panel rather than being used as a basis for disqualification. Conflicts of interest generally do require disqualification, except where outweighed by the need for a person’s services. Within these constraints, chemical industry scientists can serve important and legitimate functions on scientific advisory panels and should not be unjustifiably prevented from contributing to their work.


7. Biopesticides growing strong

AUTHOR Lerner, Ivan

SOURCE Chemical Market Reporter, v268 n20, 19 December 2005 - 8 January 2006, pp26-27

ABSTRACT With pesticide regulatory action increasing and consumers demanding more “organically” grown food, biopesticides are gaining ground as viable replacements for pesticides. Some even have the potential to replace the controversial fumigant methyl bromide. Analysts project that the biopesticides market will reach $1 billion by 2010. The average pesticide is a synthetic that needs to be used in large doses, and it usually directly kills the specific pest. Biopesticides, on the other hand, are derived from natural materials such as animals, plants, bacteria and certain minerals. Biopesticides are said to be effective in smaller doses and to have a quicker rate of decomposition than synthetic pesticides. According to the US Environmental Protection Agency (EPA), even canola oil and baking soda have pesticidal applications and are considered biopesticides. There are three kinds of biopesticides: microbial, plant-incorporated, and biochemical. Microbial pesticides consist of a microorganism (such as a bacterium, fungus, virus or protozoan) as the active ingredient. Plant-incorporated protectants are pesticidal substances that plants produce from genetic material that has been added to the plant. Biochemical pesticides are naturally occurring substances that control pests by nontoxic mechanisms, including insect sex pheromones (which interfere with pest mating), as well as various scented plant extracts that attract insects into traps.


8. Concentrations of surface-dust metals in Native American jewelry-making homes in Zuni Pueblo, New Mexico

AUTHOR  Gonzales M; Shah V.; Bobelu A.; Qualls, C; Natachu, K; Bobelu, J.; Jamon, E.; Neha, D.; Paine, S.; Zager, P.

SOURCE Archives of Environmental Health, v59 n5, May 2004, pp245-249

ABSTRACT This pilot study was conducted to identify the metals used by home-based Native American jewelry makers, to quantify the metals in dust samples taken from jewelers' homes, and to compare these concentrations with background levels from control homes in which jewelry was not made. Participants were recruited from Zuni Pueblo, New Mexico. Surface dust samples were collected from the work and living areas of 20 jewelers' homes, and from the living areas of 20 control homes. Silver, copper, tin, boron, nickel, zinc, lead, and cadmium were significantly higher in work areas than in living areas of jewelry-making homes (p < or = 0.02). Silver, copper, nickel, and antimony were significantly higher in living areas of jewelers' homes compared with control homes (p < or = 0.04). Ventilation measures did not effectively reduce metal concentrations in jewelers' homes; concentrations in nonwork areas remained elevated.


9. Additives Annual: Enhancing Performance, Versatility and Processability of Polymers

AUTHOR Stewart, Richard

SOURCE Plastics Engineering, v61 n11, November 2005, pp18-30

ABSTRACT Plastics additives enhance the performance, versatility, and processability of polymers. They enable resins to be tailored to meet the precise needs of applications—strengthened by adding reinforcements, given a unique look by introducing colorants and other aesthetic property modifiers, made resistant to harmful environmental effects through the addition of stabilizers. This report covers recent developments in the major additive categories, with the exception of flame retardants, which will be the subject of a feature article in the February 2006 issue of Plastics Engineering. Products are grouped alphabetically by functional type and manufacturer.


10. Toxic at Any Speed: Chemicals in Cars and the Need for Safer Alternatives

AUTHOR Gearhart, Jeff; Posselt, Hans

SOURCE The Ecology Center

DATE 2006

ABSTRACT When most people think about auto safety, seatbelts and air bags likely come to mind. But cars also pose hidden hazards that endanger drivers and passengers even before turning on the ignition. Chemicals used to make seat cushions, arm rests, floor coverings and plastic parts can break down into toxic dust that is inhaled, becoming a serious health risk. According to the Environmental Protection Agency (EPA), indoor air pollution is one of the top five environmental risks to public health. Next to homes and offices, Americans spend the greatest amount of time in their cars—more than 100 minutes per day on average. This study by the Ecology Center, Toxic at Any Speed: Chemicals in Cars & the Need for Safe Alternatives, found that concentrations of some toxic chemicals in automobile interiors were five to ten times higher than those found in homes and offices, thus making cars a significant contributor to overall indoor air pollution. The report examines two classes of toxic compounds: polybrominated diphenyl ethers (PBDEs) and phthalic acid esters (phthalates). PBDEs, used as flame retardants, and phthalates, used to soften plastics, were chosen due to their toxicity and ubiquity in the environment.

 

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This page updated Friday January 20 2006