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Greenlist(tm) Bulletin 02/03/2006


This is the weekly bulletin of the TURI Library, reporting a selection of recently published titles we have acquired. Our pledge is to keep the bulletin relevant to your work and brief -- no more than 10 titles. You are welcome to send a message to jan@turi.org if you would like more information on any of the articles listed here.

Titles here, abstracts below them:
  1. Learning from the Solutia EMS Experience: Improving an Environmental Management System at the Solutia, Inc. Indian Orchard Plant in Springfield, Massachusetts
  2. EU bends on detergents directive: Legislators consider the problems caused by stricter rules
  3. Pesticides and Parkinson's Disease--Is There a Link?
  4. The Sweet Smell of Nano-success: Cleaner Method Of Making Spices, Perfumes Moves One Step Closer To Reality
  5. FloorScore IAQ Testing Program Launched
  6. Market-Led Versus Government-Facilitated Growth: Development of the U.S. and EU Organic Agricultural Sectors
  7. ‘Reverse’ tanning process could revolutionize leather industry
  8. Organising Life-cycles in Supply Chains
  9. State of the Evidence: What is the Connection Between the Environment and Breast Cancer?
  10. Significant Residual Fluorinated Alcohols Present in Various Fluorinated Materials

1. Learning from the Solutia EMS Experience: Improving an Environmental Management System at the Solutia, Inc. Indian Orchard Plant in Springfield, Massachusetts

AUTHOR Clark, Janet; Collins, Jeff; Hart, Roy; Mason, Chuck

SOURCE Toxics Use Reduction Institute (TURI)

DATE 2005

ABSTRACT The Solutia, Inc. Indian Orchard Plant in Springfield, Massachusetts (Solutia IO) is currently improving an existing environmental management system (EMS) and certifying it to the ISO 14001 standard, primarily because its customers are demanding it. In the fall of 2004, Solutia IO received a grant from the Massachusetts Toxics Use Reduction Institute (TURI) to host a series of meetings for a work group of peers -- lead staff from other Massachusetts companies working on EMS projects. At that time, Solutia IO hired experts from Gannett Fleming and began an aggressive program of gap analysis, planning, documentation and training to prepare for the third party audit. Although the EMS team realized that its proactive environmental programs already met many ISO 14001 requirements the team uncovered shortcomings in key environmental areas. The project has led to improvement in the plant’s environmental performance while reducing its risks, and the TURI peer mentoring work group proved valuable in fielding ideas and comparing best practices. In 2005, the plant was among the select group recognized by the State of Massachusetts’ Toxic Use Reduction Institute (TURI) as a “Champion of Toxics Use Reduction” for its leadership in the industry Peer Mentoring EMS Work Group.


2. EU bends on detergents directive: Legislators consider the problems caused by stricter rules

SOURCE Chemical Market Reporter, v269 n4, 30 January-5 February 2006

ABSTRACT Producers of specialized, industrial-strength detergents may get a temporary reprieve on the so-called detergents directive, the new regulation on biodegradability that the EU began implementing last fall. The rules have posed little difficulty for manufacturers of household detergents because surfactants used in consumer products have for some time met the new biodegradability standards. But it has worried some small and medium-sized businesses (SMEs) providing specialty detergents for industrial and institutional (I&I) customers. So the two arms of the EU legislature—the European Parliament and the Council of Ministers representing the governments of the union’s 25 member states—were persuaded to allow for exemptions or derogations for low-volume surfactants that meet certain environmental criteria. The vast majority of surfactants under the legislation will have to demonstrate ultimate biodegradability of 60 percent mineralization as carbon dioxide, water and mineral salts within 28 days. But surfactants in I&I detergents will be entitled to a derogation if they have a level of primary biodegradability of at least 80 percent, do not form recalcitrant metabolites, and do not present an unacceptable danger to the environment, after a risk assessment.


3. Pesticides and Parkinson's Disease--Is There a Link?

AUTHOR Brown, Terry P.; Rumsby, Paul C.; Capleton, Alexander C.; Rushton, Lesley; Levy, Leonard S.

SOURCE Environmental Health Perspectives, v114 n2, February 2006, pp156-164

ABSTRACT Parkinson's disease (PD) is an idiopathic disease of the nervous system characterized by progressive tremor, bradykinesia, rigidity, and postural instability. It has been postulated that exogenous toxicants, including pesticides, might be involved in the etiology of PD. In this article we present a comprehensive review of the published epidemiologic and toxicologic literature and critically evaluate whether a relationship exists between pesticide exposure and PD. From the epidemiologic literature, there does appear to be a relatively consistent relationship between pesticide exposure and PD. This relationship appears strongest for exposure to herbicides and insecticides, and after long durations of exposure. Toxicologic data suggest that paraquat and rotenone may have neurotoxic actions that potentially play a role in the development of PD, with limited data for other pesticides. However, both the epidemiology and toxicology studies were limited by methodologic weaknesses. Particular issues of current and future interest include multiple exposures (both pesticides and other exogenous toxicants), developmental exposures, and gene-environment interactions. At present, the weight of evidence is sufficient to conclude that a generic association between pesticide exposure and PD exists but is insufficient for concluding that this is a causal relationship or that such a relationship exists for any particular pesticide compound or combined pesticide and other exogenous toxicant exposure.


4. The Sweet Smell of Nano-success: Cleaner Method Of Making Spices, Perfumes Moves One Step Closer To Reality

SOURCE ScienceDaily, www.sciencedaily.com, January 30, 2006

ABSTRACT Materials scientists at Lehigh University and catalyst chemists at Cardiff University have uncovered secrets of the "nanoworld" that promise to lead to cleaner methods of producing, among other things, spices and perfumes. The materials scientists, headed by Christopher Kiely of Lehigh, have determined the structure of a type of gold-palladium nanoparticle, which is the active component of a new environmentally friendly catalyst that promotes the oxidation of primary alcohols to aldehydes. The oxidation of primary alcohols to aldehydes is of fundamental importance to the chemical, pharmaceutical and perfume industries. The oxidation of aromatic primary alcohols, such as vanillyl and cinnamyl alcohol, is of particular importance in the manufacture of perfumes and flavorings. Almost 95 percent of the worlds' vanilla (vanillyl aldehyde) is synthetically manufactured. Benzaldehyde is also a key intermediate in the production of many fine chemicals in the agrochemical and pharmaceutical industries. Such oxidation reactions have always been performed using permanganates or chromates, but these reagents are expensive and have serious toxicity issues associated with them. This new catalyst, consisting of gold-palladium nanoparticles dispersed on a titanium oxide support, allows this reaction to take place using oxygen under mild solvent-free conditions.


5. FloorScore IAQ Testing Program Launched

SOURCE Environmental Building News, v14 n10, October 2005, p5

ABSTRACT The Resilient Floor Covering Institute (RFCI) now has its own green label for flooring products that meet low indoor emission standards. The FloorScore™ label can be found on vinyl and linoleum flooring from a half-dozen manufacturers, and the list is likely to grow. “We started with this program four years ago,” says Bill Freeman, a consultant to RFCI. “We have been testing a lot of products. Changes were made to make sure that products would meet the requirements of the California standards,” Freeman reports. FloorScore certification is handled by an independent third party, Scientific Certification Systems, Inc. (SCS). In accordance with its SCS-EC-10- 2004 Indoor Air Quality Performance standard, SCS performs site visits to verify raw material inputs and certifies products based on test results from the laboratories.


6. Market-Led Versus Government-Facilitated Growth: Development of the U.S. and EU Organic Agricultural Sectors

AUTHOR Dimitri, Carolyn; Oberholtzer, Lydia

SOURCE United States Department of Agriculture (USDA), Economic Research Service (ERS)

DATE 2005

ABSTRACT Organic farmland and sales are rapidly growing worldwide, and the two largest markets are in the European Union (EU) and the United States. The two regions have adopted different policy approaches to organic agriculture. Many EU countries have “green payments” available for transitioning and continuing organic farmers, as well as a variety of other supply and demand policies aimed at promoting growth of the organic sector. The U.S. Government, in contrast, has largely taken a free-market approach to the organic sector, and policy is aimed at facilitating market development. This report compares EU and U.S. organic agriculture policy and examines the organic sectors in the two regions.


7. ‘Reverse’ tanning process could revolutionize leather industry

SOURCE American Chemical Society News Service, January 19, 2006

ABSTRACT A new ‘greener’ and cleaner chemical process* could revolutionize the leather-tanning industry. ‘Reverse’ leather tanning, which essentially works backward from the point where conventional tanning ends, saves time, money and energy while drastically slashing water use and pollution, say researchers at the Central Leather Research Institute in Adyar, India. From pre-tanning to finishing, conventional leather tanning requires about 15 steps, which produce enormous amounts of wastewater and pollutants, including sulfides, chlorides, sulfates and other compounds. The new approach flips the process around and eliminates some of the steps, which results in multiple and substantial production efficiencies, the researchers say. In the new process, for instance, prior to tanning, the skins are treated with chemicals normally used after tanning is completed. According to the researchers, the reverse process produces leather that is comparable to conventional tanning, but requires 42 percent less time, 54 percent fewer chemicals, 42 percent less energy, 65 percent less water and cuts emissions of key pollutants by up to 79 percent. The results were achieved without changing chemicals or using new ones, the researchers note. In addition to costing less and being “greener” than conventional tanning, the reverse process is “easy-to-adopt” and could help the global industry overcome emerging environmental and economic concerns, the researchers conclude.


8. Organising Life-cycles in Supply Chains

AUTHOR Hagelaar, Geoffrey J.L.F.; van der Vorst, Jack G.A.J.; Marcelis, Willem J.

SOURCE Greener Management International, Issue 45, Spring 2004, pp27-42

ABSTRACT In recent years increasing attention has been given to continual environmental performance improvement. Although we support the thesis that organisations are able to continuously improve their environmental performance, we state that truly higher levels of environmental care are reached only via fundamental organisational changes. We conclude that, in the literature, attention to a direct link between two important dimensions of corporate environmental improvement—environmental management concepts and environmental performance—lags behind. This linkage is considered to be a critical success factor for the establishment of truly higher environmental performances. The leading principle is that of environmental care strategies in which environmental targets and organisational activities to reach those targets are linked. Three environmental care strategies are presented. The linkage means that when a company or chain of companies wants to improve on its environmental performance and changes its environmental care strategy, fundamental organisational changes are required.


9. State of the Evidence: What is the Connection Between the Environment and Breast Cancer?

AUTHOR Evans, Nancy (ed.)

SOURCE Breast Cancer Fund and Breast Cancer Action

DATE 2006

ABSTRACT Breast cancer rates have been climbing steadily in the United States and other industrialized countries since the 1940s, amounting to more than one million cases per year worldwide. In the United States, a woman’s lifetime risk of breast cancer has nearly tripled during the past four decades. Less than one out of every 10 cases occurs in women born with a genetic predisposition for the disease, and as many as half of all breast cancers occur in women who have no known risk factors for the disease. This State of the Evidence report demonstrates that a significant body of scientific evidence links exposure to radiation and synthetic chemicals to an increased risk of breast cancer. It summarizes the findings of more than 350 experimental, epidemiologic and ecological studies and describes some of the ongoing controversies in breast cancer research. The report recommends new directions for future research and includes a 10-point plan to act on the evidence and reduce human exposure to radiation and synthetic chemicals. This plan is based primarily on the precautionary principle, which in part states that indication of harm, not just proof of harm, is grounds for action.


10. Significant Residual Fluorinated Alcohols Present in Various Fluorinated Materials

AUTHOR Dinglasan-Panlilio, Mary Joyce A.; Mabury, Scott A.

SOURCE Environmental Science & Technology Research ASAP, January 25, 2006

ABSTRACT Polyfluorinated telomer alcohols and sulfonamides are classes of compounds recently identified as precursor molecules to the perfluorinated acids detected in the environment. Despite the detection and quantification of these volatile compounds in the atmosphere, their sources remain unknown. Both classes of compounds are used in the synthesis of various fluorosurfactants and incorporated in polymeric materials used extensively in the carpet, textile, and paper industries. This study has identified the presence of residual unbound fluoro telomer alcohols (FTOHs) in varying chain lengths (C6-C14) in several commercially available and industrially applied polymeric and surfactant materials. NMeFOSE, a perfluoroalkyl sulfonamido alcohol, was also detected in a commercially available carpet protector product. A method was developed to remove these residual compounds from polymeric and surfactant materials by dispersion in water and stripping of the volatiles using a constant flow of air and trapping on XAD resin. Using gas chromatography mass spectrometry analysis, it was determined that the fluorinated materials examined consist of 0.04-3.8% residual alcohols on a fluoro alcohol to dry mass basis. These values indicate that residual alcohols, left unreacted and unbound from the manufacturing process of fluorinated polymers and surfactants, could be a significant source of the polyfluorinated telomer alcohols and sulfonamides released into the environment. This study suggests that elimination or reduction of these residual alcohols from all marketed fluorinated polymers and fluorosurfactants is key in reducing the prevalence of perfluorinated acids formed in the environment.

 

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This page updated Thursday February 09 2006