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Greenlist(tm) Bulletin 02/24/2006


This is the weekly bulletin of the TURI Library, reporting a selection of recently published titles we have acquired. Our pledge is to keep the bulletin relevant to your work and brief -- no more than 10 titles. You are welcome to send a message to jan@turi.org if you would like more information on any of the articles listed here.

Titles here, abstracts below them:
  1. New nano-canary in the nanotoxicology coalmine: the body itself
  2. CRS Report for Congress: Persistent Organic Pollutants (POPS): Fact Sheet on Three International Agreements
  3. VTT Technical Research Centre of Finland develops high-technology ecological paper
  4. Human Breast Milk Contamination with Phthalates and Alterations of Endogenous Reproductive Hormones in Infants Three Months of Age
  5. Environmental Credit Trading: Can Farming Benefit?
  6. The Turtle and the Hare: Beating the RoHS Deadline Anyway
  7. Proposed Risk Assessment Bulletin
  8. Study Quantifies Personal Exposure to Air Pollution
  9. Perfluorochemicals in Pooled Serum Samples from United States Residents in 2001 and 2002

1. New nano-canary in the nanotoxicology coalmine: the body itself

SOURCE Pacific Northwest National Laboratory NewsRoom, www.pnl.gov/news/, February 17, 2006

ABSTRACT There is growing consensus among scientists, regulators, politicians, industry and the public that we need to know more about the possible harmful or adverse effects of nanoparticles on human health. Likewise, most agree that these incredibly small materials can behave quite differently from conventional materials. Nonetheless, neighborhood stores feature products that promise benefits from these near-atomic level materials, from paints and cosmetics to toothpaste and sunscreens. But, could we be putting human health at risk by exposing consumers to potentially toxic materials? To investigate the damage potential of sub-micron sized particles, S.K. Sundaram and Thomas J. Weber, scientists at the Department of Energy’s Pacific Northwest National Laboratory in Richland, Wash., have harnessed living cells to monitor responses to a variety of toxins. “The process requires that live cells be grown on an infrared transparent substrate giving us an opportunity to closely examine the biological effects in living cells,” said Sundaram. Live cell Fourier transform infrared, FTIR, spectroscopy offers several attractive features for these investigations. These include the potential to detect biologically active nanoparticles without any prior knowledge of cell signaling pathways affected by them or need of a contrast agent to detect the biological response. Thus, live cell FTIR spectroscopy is expected to be a sentinel of exposure to help define nanoparticles that are biologically active, without bias of what that biological activity represents.


2. CRS Report for Congress: Persistent Organic Pollutants (POPS): Fact Sheet on Three International Agreements

AUTHOR Schierow, Linda-Jo

SOURCE Congressional Research Service, February 15, 2006

ABSTRACT Persistent organic pollutants (POPs) are chemicals that do not break down easily in the environment, tend to accumulate as they move up the food chain, and may be harmful to people and wildlife. Between 1998 and 2001, the United States signed two international treaties and one executive agreement to reduce the production and use of POPs and to regulate the trade and disposal of them. The President has signed and submitted the two treaties to the Senate for advice and consent. If the Senate consents by a two-thirds majority, and if Congress passes legislation needed to implement the treaties and the executive agreement in the United States, then the treaties can be ratified and the agreements would become binding U.S. law. Legislation has been introduced into the 109th Congress that would allow implementation of the agreements. H.R. 4591 would amend the Toxic Substances Control Act, which governs industrial uses of chemicals; H.R. 3849 and S. 2042 would amend the Federal Insecticide, Fungicide, and Rodenticide Act, which regulates the sale and use of pesticides. Prospects for passage are not yet clear. This report will be updated as warranted.


3. VTT Technical Research Centre of Finland develops high-technology ecological paper

SOURCE VTT Technical Research Centre of Finland

DATE 2006

ABSTRACT VTT Technical Research Centre of Finland has developed natural materials from raw starch, which helps to make very high-quality paper that is fully recyclable. Due to the materials used for filling, adhesive and coating purposes, paper developed from starch is 20 to 30 per cent lighter, which means a reduction in transport costs too. The new raw materials and methods developed by VTT have drawn particular international interest, because fully recyclable paper supports sustainable development and opens totally new perspectives on reducing the environmental impacts of paper products. After recycling, the components of starch-based paper can be fully converted to bioenergy with less emissions than the conventional paper. With the help of internationally unique new technology, starch can technically replace the mineral (rock-based) filling and adhesive materials of paper. Even partially replacing minerals with starch improves the surface strength of paper and makes it easier to print on. Starch also helps to achieve better colour rendering. In addition, it is easier to make starch paper glossy, which reduces the finishing costs. Costs are further reduced by the fact that paper-finishing devices (calenders) wear less because there are fewer or no minerals in the paper. VTT has developed the new raw materials chemically from potato starch. With the new raw materials it is possible to replace some of expensive oil-based binder materials, and there are also applications in the paint and plastic industries. However, the production costs of the new raw materials are high at the moment.


4. Human Breast Milk Contamination with Phthalates and Alterations of Endogenous Reproductive Hormones in Infants Three Months of Age

AUTHOR Main, Katharina M.; Mortensen, Gerda K.; Kaleva, Marko M.; et al.

SOURCE Environmental Health Perspectives, v114 n2, February 2006, pp270-276

ABSTRACT Phthalates adversely affect the male reproductive system in animals. We investigated whether phthalate monoester contamination of human breast milk had any influence on the postnatal surge of reproductive hormones in newborn boys as a sign of testicular dysgenesis. DESIGN: We obtained biologic samples from a prospective Danish–Finnish cohort study on cryptorchidism from 1997 to 2001. We analyzed individual breast milk samples collected as additive aliquots 1–3 months postnatally (n = 130; 62 cryptorchid/68 healthy boys) for phthalate monoesters [mono-methyl phthalate (mMP), mono-ethyl phthalate (mEP), mono-n-butyl phthalate (mBP), mono-benzyl phthalate (mBzP), mono-2-ethylhexyl phthalate (mEHP), mono-isononyl phthalate (miNP)]. We analyzed serum samples (obtained in 74% of all boys) for gonadotropins, sex-hormone binding globulin (SHBG), testosterone, and inhibin B. RESULTS: All phthalate monoesters were found in breast milk with large variations [medians (minimum–maximum)]: mMP 0.10 (< 0.01–5.53 µg/L), mEP 0.95 (0.07–41.4 µg/L), mBP 9.6 (0.6–10,900 µg/L), mBzP 1.2 (0.2–26 µg/L), mEHP 11 (1.5–1,410 µg/L), miNP 95 (27–469 µg/L). Finnish breast milk had higher concentrations of mBP, mBzP, mEHP, and Danish breast milk had higher values for miNP (p = 0.0001–0.056). No association was found between phthalate monoester levels and cryptorchidism. However, mEP and mBP showed positive correlations with SHBG (r = 0.323, p = 0.002 and r = 0.272, p = 0.01, respectively); mMP, mEP, and mBP with LH:free testosterone ratio (r = 0.21–0.323, p = 0.002–0.044) and miNP with luteinizing hormone (r = 0.243, p = 0.019). mBP was negatively correlated with free testosterone (r = –0.22, p = 0.033). Other phthalate monoesters showed similar but nonsignificant tendencies. CONCLUSIONS: Our data on reproductive hormone profiles and phthalate exposures in newborn boys are in accordance with rodent data and suggest that human Leydig cell development and function may also be vulnerable to perinatal exposure to some phthalates. Our findings are also in line with other recent human data showing incomplete virilization in infant boys exposed to phthalates prenatally.


5. Environmental Credit Trading: Can Farming Benefit?

AUTHOR Ribaudo, Marc; Johansson, Robert; Jones, Carol

SOURCE Amber Waves, www.ers.usda.gov/AmberWaves/February06/, February 2006

ABSTRACT Environmental regulations often require firms that emit pollutants to limit emissions to a set level or to install specific emission-reducing technologies. While fairly straightforward, this command-and-control approach can be costly both to the firms and to society. Firms with high costs of pollution reduction and those with low costs are required to meet the same requirements, which may waste resources. Environmental credit trading, an alternative to command-and-control regulations, is a market-based approach to comply with regulations that could achieve pollution abatement goals at lower costs to society. Environmental credit trading allows regulated firms to meet their obligations by purchasing pollution abatement services (credits) from lower-cost providers. For example, the 1990 Clean Air Act amendments established a trading program between power plants to cut sulfur dioxide (SO2) emissions by 50 percent from 1980 levels to control acid rain. The trading program has been a success, with emissions reductions exceeding the goal by 30 percent and annual cost savings estimated at $1 billion. Trading programs have been created for environmental issues other than air quality, such as water quality, wetlands protection, and greenhouse gas emissions. Even though agriculture per se is not subject to most environmental regulations, farmers can participate in these credit trading programs by generating pollution-reduction credits and selling them to regulated firms. Farmers can benefit if the cost of generating credits is less than the price they command. Farmer participation in trading programs has been limited to date, but USDA has recently committed to promoting farmers’ participation in trading programs. The success of these programs will rest on several key design elements and their ability to generate the economic incentives needed to encourage both the regulated firms and farmers to participate.


6. The Turtle and the Hare: Beating the RoHS Deadline Anyway

AUTHOR Biocca, Peter

SOURCE Global SMT & Packaging, v6 n2, February 2006, pp20-22

ABSTRACT Another year has begun, and with the impending July 1st 2006 deadline for the RoHS Directive rapidly approaching, some companies are experiencing the stresses involved in meeting their obligations. Some assemblers have been looking at lead-free soldering for many years and are making lead-free products; others have gathered valuable information in the last year; and still others are just starting to look at lead-free and RoHS. The last year has been a great year for lead-free and RoHS information, and the numerous conferences, seminars, papers, technical articles and web-casts have been a little overwhelming. A substantial amount of very good information is now available to the assembler wishing to transition. This was not the case a year ago when solder alloy confusion still reigned. This article reviews the current status of lead-free and gives the latest information for those companies still making the transition.


7. Proposed Risk Assessment Bulletin

SOURCE United States Office of Management and Budget (OMB), January 9, 2006

ABSTRACT As part of an ongoing effort to improve the quality, objectivity, utility, and integrity of information disseminated by the federal government to the public, the Office of Management and Budget (OMB), in consultation with the Office of Science and Technology Policy (OSTP), proposes to issue new technical guidance on risk assessments produced by the federal government. Interested parties should submit comments to OMB’s Office of Information and Regulatory Affairs on or before June 15, 2006. Risk assessment is a useful tool for estimating the likelihood and severity of risks to human health, safety and the environment and for informing decisions about how to manage those risks. For the purposes of this Bulletin, the term “risk assessment” refers to a document that assembles and synthesizes scientific information to determine whether a potential hazard exists and/or the extent of possible risk to human health, safety or the environment. The acceptance of risk assessment in health, safety, and environmental policy was enhanced by the seminal report issued by the National Academy of Sciences (NAS) in 1983: Risk Assessment in the Federal Government: Managing the Process. The report presented a logical approach to assessing environmental, health and safety risk that was widely accepted and used by government agencies. Over twenty years after publication of the NAS report, there is general agreement that the risk assessment process can be improved. The process should be better understood, more transparent and more objective. Risk assessment can be most useful when those who rely on it to inform the risk management process understand its value, nature and limitations, and use it accordingly. OMB, in collaboration with OSTP, has a strong interest in the technical quality of agency risk assessments because these assessments play an important role in the development of public policies at the national, international, state and local levels. The increasing importance of risk assessment in the development of public policy, regulation, and decision making requires that the technical quality and transparency of agency risk assessments meet high quality standards. Moreover, a risk assessment prepared by one federal agency may inform the policy decisions of another federal agency, or a risk assessment prepared by one or more federal agencies may inform decisions made by legislators or the judiciary. This Bulletin builds upon the historic interest that both OMB and OSTP have expressed in advancing the state of the art of risk assessment. The purpose of this Bulletin is to enhance the technical quality and objectivity of risk assessments prepared by federal agencies by establishing uniform, minimum standards.


8. Study Quantifies Personal Exposure to Air Pollution

SOURCE Mickey Leland National Urban Air Toxics Research Center, November 18, 2005

ABSTRACT A study published by the Mickey Leland National Urban Air Toxics Research Center and the Health Effects Institute has found that both outdoor and indoor air sources can contribute to personal exposure to air pollution. The study, Relationships of Indoor, Outdoor, and Personal Air (or RIOPA), measured levels of air toxics and particulate matter (PM2.5*) in outdoor air, indoor air, and the personal breathing zone for 100 adult subjects and their homes in each of three US cities: Los Angeles, California, Houston, Texas, and Elizabeth, New Jersey. In vehicle concentrations of certain air toxics were also measured. Each city had a different source profile as home were monitored close to freeways in Los Angeles, near petrochemicals in Houston and a mixture of sources such as freeways , dry cleaners, and gas stations in Elizabeth. The study, conducted by Drs Clifford P Weisel, Junfeng (Jim) Zhang, and Barbara J Turpin of the Environmental and Occupational Health Sciences Institute at Rutgers University in New Jersey along with scientists in California and Texas, found that, with a few important exceptions, personal and indoor levels of some of the 16 volatile organic compounds and 10 aldehydes measured were higher than outdoor levels. The finding that personal exposure concentrations were higher than outdoor concentrations for most of the species measured indicates that indoor sources contribute to, and in some cases dominate, personal exposure.


9. Perfluorochemicals in Pooled Serum Samples from United States Residents in 2001 and 2002

AUTHOR Calafat, Antonia M.; Kuklenyik, Zsuzsanna; Caudill, Samuel P.; Reidy, John A.; Needham, Larry L.

SOURCE Environmental Science & Technology ASAP, February 22, 2006

ABSTRACT Manufacturers have used perfluorochemicals (PFCs) since the 1950s in many industrial and consumer products, including protective coatings for fabrics and carpet, paper coatings, insecticide formulations, and surfactants. Some PFCs are persistent ubiquitous contaminants in the environment and in humans. Exposures to PFCs result in potential developmental and other adverse effects in animals. The sources of human exposure to PFCs and the potential health risks associated with exposure are still unclear, and differences in patterns of human exposure may vary. We measured the serum concentrations of perfluorooctane sulfonic acid (PFOS), perfluorooctanoic acid (PFOA; C8), perfluorohexane sulfonic acid (PFHxS), and 8 other PFCs in 54 pooled serum samples collected from 1832 participants of the 2001-2002 National Health and Nutrition Examination Survey. Participants were 12 years of age and older. The pools represented three major racial groups/ ethnicities (non-Hispanic blacks, non-Hispanic whites, and Mexican Americans), four age categories (12-19 years, 20-39 years, 40-59 years, and 60 years and older), and both genders. PFCs were extracted from 100 íL of serum using on-line solid-phase extraction coupled to isotope dilution-high performance liquid chromatography-tandem mass spectrometry. The limits of detection ranged from 0.05 ng/mL to 0.2 ng/mL. The concentrations of most PFCs were similar among the four age groups. For PFOS, the estimated least-squares mean (LSM) concentrations among non-Hispanic white males (40.19 ng/mL) and females (23.97 ng/mL) were greater than among non-Hispanic black males (18.27 ng/mL) and females (17.93 ng/mL) or Mexican American males (13.71 ng/mL) and females (10.40 ng/ mL). Similarly, for PFOA, the LSM concentrations among non- Hispanic white males (6.98 ng/mL) and females (3.97 ng/ mL) were greater than among non-Hispanic black males (3.62 ng/mL) and females (2.85 ng/mL) or Mexican American males (2.89 ng/mL) and females (2.08 ng/mL). Non-Hispanic whites had also greater LSM concentrations of PFHxS than non-Hispanic blacks and Mexican Americans. These findings indicate different patterns of human exposure to PFCs among the population groups examined and stress the importance of conducting research to identify the environmental sources and pathways of human exposure to PFCs.

 

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Compiled by the TURI Library, University of Massachusetts Lowell



This page updated Friday March 03 2006