University Research in Sustainable Technologies
The following reports summarize the results of research into sustainable technologies conducted by UMass faculty and students using TURI grant funding.
|
|
Dr. Daniel Schmidt, and his research team from the Department of Plastics Engineering at UMass Lowell, in collaboration with industry partner Teknor Apex, demonstrate performance of PVC formulations that do not use the toxic chemicals lead or phthalates. TURI Technical Report No. 60.
Download PDF file
(1.09 MB)
|
|
|
TURI Technical Report No. 58. The goal of this project is the production of high-performance, low-cost lead-free PVC compounds for wire and cable insulation, to address the serious environmental issues surrounding the use of their leaded counterparts and the lack of market acceptance of current alternatives to PVC. Clay nanocomposite technology has been chosen as a means to achieve this goal, as it has been demonstrated that such
systems can improve a variety of properties relevant to the performance of wire and cable insulation (thermal stability, barrier properties, flame retardance, etc.). Here we report on the characterization of transparent, lead-free PVC nanocomposites produced by melt blending with organoclay loadings of 2, 5, and 10 wt%. Structural studies carried out via x-ray diffraction indicate significant intercalation as well as orientation of the clay sheets in the flow direction. From MOCON testing, nanocomposites with 2 wt% clay showed a five-fold increase in oxygen barrier. While a substantial improvement in thermal stability was not observed in TGA experiments, the greatly improved oxygen barrier properties may nevertheless enhance thermal stability in real-world settings. From mechanical properties testing, the modulus of the PVC/nanocomposite was found to increase with clay content; nevertheless, 2 wt% was found to be the optimal loading level due to the degradation of ultimate properties with higher clay content.
Download PDF file
(579.60 kB)
|
|
|
TURI Technical Report No. 56. New regulations have led to the need for non-lead compounds to be used in wire and cable applications. There are two approaches for lead free EPDM wire and cable compounds. One is to find alternative stabilizers, and the other is to change resins. In a previous study, hydrotalcite was examined as a replacement for lead additives in applications using Ziegler-Natta based EPDM, and was very effective as an alternative stabilizer. In this research, the metallocene based EPDM was investigated as a potential replacement elastomer, which would not require lead stabilization.
Download PDF file
(502.78 kB)
|
|
|
TURI Technical Report No. 57. The textile industry produces and uses approximately 1.3 million tonnes of dyes, pigments and dye precursors, valued at around $23 billion, almost all of which is manufactured synthetically. However, synthetic dyes have some limitations, primarily, (i) their production process requires hazardous chemicals, creating worker safety concerns, (ii) they may generate hazardous wastes, and (iii) these dyes are not environmentally friendly. This research explores methods where natural dyes are produced from plant tissue and fungal species.
Download PDF file
(378.90 kB)
|
|
|
TURI Technical Report No. 54. The explosion of the information age has led to a scramble to increase the infrastructure of data carrying capacity. The building industry has seen a large increase in the demand for new housing. The electronic market continues to grow at an astounding pace. All of these industries require insulating wire for use in their products. As the amount of wire products increase special attention must be paid to the impact which these products make on the environment. Lately attention has been focused on polyvinyl chloride or PVC. New legislation in places such as California and Europe have begun to regulate the use of substances that are common additives to PVC. This project proposes to research the technical, economic and environmental feasibility of using alternative resins to PVC in the wire and cable industry.
Download PDF file
(436.70 kB)
|
|
|
TURI Technical Report No. 52. Researchers on this project formed an industry-led "UMASS Lead-Free Consortium" (the Consortium) of local and national companies to evaluate various emerging alternatives to lead-based solders and finishes. The consortium members donated expertise, time, materials and equipment to this project. The various alternatives to lead-bearing materials, surface finishes and manufacturing processes were evaluated as factors in a set of designed experiments, and compared the results to a baseline of standard leaded processes and materials, using the quality characteristics of visual, mechanical and thermal testing criteria. The Manufacturing Research Laboratory facilities at UMASS Lowell were utilized to test and analyze the performance of alternatives based on the principles of Design of Experiments. Results were analyzed using statistical techniques resulting in determining whether a particular factor was significant to the quality characteristic being measured. A theoretical percent contribution to the total quality characteristic was calculated for significant factors.
Download PDF file
(307.96 kB)
|
|
|
TURI Technical Report No. 50. This study focuses on aspects of the relationship between pollution prevention (P2) and occupational health. It evaluates the effects of pollution prevention intervention programs (i.e., toxics use reduction) on worker safety and health at three Massachusetts printed wire board manufacturing facilities. Most important, it focuses on primary prevention (in the form of P2) and how this model benefits both the environment and the worker. In addition, it provides useful feedback on what motivates companies to approach environmental and occupational compliance issues as a single concern.
Download PDF file
(245.63 kB)
|
